Copolymers of 2-hydroxyethyl-methacrylate, 2-hydroxypropyl-methacrylate, or 3-chloro-2-hydroxypropyl methacrylate with acrylamide or methacrylamide having different compositions were synthesized by free radical bulk polymerization. Some of their properties, for example, density, polymerization shrin
Synthesis and swelling properties of the copolymer of acrylamide with anionic monomers
β Scribed by Wen-Jing Zhou; Ke-Jun Yao; Mark J. Kurth
- Publisher
- John Wiley and Sons
- Year
- 1996
- Tongue
- English
- Weight
- 314 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0021-8995
No coin nor oath required. For personal study only.
β¦ Synopsis
SYNOPSIS
A series of novel superabsorbent copolymers of acrylamide (AM), sodium allylsulfonate (SAS), sodium acrylate (AA), and N,N'-methylenebisacrylamide (BisA) were synthesized using potassium persulfate (KPS)/N,N,N',N'-tertramethylethylenediamine (TMEDA) as the initiator. The influences of synthetic variables (monomer concentration, temperature, initiator concentration, and pH) on the polymerization conversion ( y W ) and swelling properties were studied in detail. These gels should have potential application as water superabsorbents.
π SIMILAR VOLUMES
A monomer, diethyl a,a-dimethyl-m-isopropenylbenzyl carbamoylphosphonate, has been prepared by the base-catalyzed reaction of the isocyanate m-TMI ( a,adimethyl-m-isopropenylbenzylisocyanate) with diethyl phosphite. The structure of the carbamoylphosphonate monomer and its styrene copolymer was conf
A series of hydrogels were prepared from acrylamide and 2-acrylamido-2methylpropanesulfonic acid (AMPS) monomers with 0 -80 mol % AMPS and using N,NΠ-methylenebis(acrylamide) as the crosslinker. The swelling capacities of hydrogels were measured in water and in aqueous NaCl solutions. The volume swe