✦ LIBER ✦

Synthesis and study of a novel hybrid UV photoinitiator: p-benzoyldiphenyliodonium hexafluorophosphate (PhCOPhI+PhPF3.0.CO;2-F/asset/equation/tex2gif-stack-1.gif?v=1&t=h5ktj8zc&s=93c58afd869351567745f9b883b4610b53b1ca8c" class="inlineGraphic">)

✍ Scribed by Jun-Hui He; Vidal Salazar Mendoza

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 613 KB
Volume: 34
Category: Article
ISSN: 0887-624X
DOI: 10.1002/(sici)1099-0518(19960930)34:13<2809::aid-pola27>3.0.co;2-f

No coin nor oath required. For personal study only.

✦ Synopsis

A novel hybrid photoinitiator, p-benzoyldiphenyliodonium hexafluorophosphate (PhCOPhI+PhPF&), was synthesized, characterized, and studied. It absorbs UV light not only below 300 nm, but above 300 nm as well. When exposed to UV light, it undergoes an asymmetrical photocleavage to produce cation-radicals and radicals which could induce cationic and radical polymerizations respectively. Compared with the simple iodonium salt PhI'PhPF;, and bimolecular sensitization system PhCOPh/PhI+PhPF;, the covalently bonded photosensitization system PhCOPhI+PhPF, is much more efficient as a photoinitiator. Oxygen has a small negative effect on the cationic polymerization photoinitiated by PhCOPhI'PhPF;, while isopropanol has a small positive influence only in argon atmosphere. 0

📜 SIMILAR VOLUMES

Darstellung, Schwingungsspektren und Kri

Darstellung, Schwingungsspektren und Kristallstrukturen von [(Ph3P)2N]2[(W6Cl3.0.CO;2-F/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l55xr9&s=7fd6cbad1d12e17d0b8214b235df659b8ed0b27b" class="inlineGraphic">)I3.0.CO;2-F/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l55xr9&s=23f5f183e89bd60b5c1ec519dd63cdd97f8e7b10" class="inlineGraphic">] · 2 Et2O · 2 CH2Cl2 und [(Ph3P)2N]2[(W6Cl3.0.CO;2-F/asset/equation/tex2gif-stack-3.gif?v=1&t=h5l55xra&s=f7a09c6faa8bbee6e5e399f0d35973097893458e" class="inlineGraphic">)(NCS)3.0.CO;2-F/asset/equation/tex2gif-stack-4.gif?v=1&t=h5l55xra&s=3c671b4017e4ba7c7cb9a2d9b8080282f0121140" class="inlineGraphic">] · 2 CH2Cl2

✍ M. Stallmann; W. Preetz 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 151 KB 👁 2 views

Darstellung, Kristallstruktur und Schwin

Darstellung, Kristallstruktur und Schwingungsspektren von (n-Bu4N)2[(Mo6I3.0.CO;2-2/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l3kyw8&s=93e45d0cb4f92807997c6ebb82721d9ee990ff7f" class="inlineGraphic">)(NCS)3.0.CO;2-2/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l3kyw8&s=c5cd1815a7ed012b140d6087a0e5b6b479347b00" class="inlineGraphic">]

✍ M. Höhling; M. K. Simsek; W. Preetz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 125 KB 👁 2 views

Inhaltsu È bersicht. Bei der Umsetzung von [(Mo 6 I i 8 )I a 6 ] 2± mit (SCN) 2 in Dichlormethan bei ±20 °C entsteht das Hexaisothiocyanato-Clusteranion [(Mo 6 I i 8 )(NCS) a 6 ] 2± . Die Ro È ntgenstrukturanalyse an einem Einkristall von (n-Bu 4 N) 2 [(Mo 6 I i 8 )(NCS) a 6 ] ´2 Me 2 CO (monoklin,

Iodostannate mit polymeren Anionen: (Me3

Iodostannate mit polymeren Anionen: (Me3PhN)4 3.0.CO;2-7/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l53ly8&s=50a18ccd2d2674c85cdb6be9fde5fcdbf5bb947b" class="inlineGraphic">[Sn3I10], [Me2HN–(CH2)2–NMe2H]2 3.0.CO;2-7/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l53ly8&s=dc8bfbdbe1527b5ced27efbb7b9d5f22fed1be4a" class="inlineGraphic">[Sn3I10] und [Me2HN–(CH2)2–NMe2H]3.0.CO;2-7/asset/equation/tex2gif-stack-3.gif?v=1&t=h5l53ly9&s=5f91c32943544de15df9dc2ea0ba7b50a1f3fec2" class="inlineGraphic">[Sn3I8]

✍ Christine Lode; Harald Krautscheid 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 140 KB 👁 2 views

An ab initio study of the structures and

An ab initio study of the structures and properties of the XH3.0.CO;2-6/asset/equation/tex2gif-stack-1.gif?v=1&t=h5o1u01t&s=f0564d329b3a20ba93f50bb114b0b5f43bd4e66a" class="inlineGraphic"> and XH3.0.CO;2-6/asset/equation/tex2gif-stack-2.gif?v=1&t=h5o1u01t&s=3028c085e80f7af45e0c371525a02839db9e470b" class="inlineGraphic"> (X=C, Si, Ge) dications

✍ Peter Babinec; Jerzy Leszczynski 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 206 KB 👁 3 views

The ab initio electronic structure calculations at the MP2 and the Becke Ž . 3LYP density functional levels in conjunction with the 6-311qqG 2 df, 2 pd basis set were used for the determination of the structure, vibrational spectra, and dissociation 2q 2q Ž . energies of the XH and XH X s C, Si, Ge

Darstellung, Kristallstrukturen und Schw

Darstellung, Kristallstrukturen und Schwingungsspektren von [OsBr3.0.CO;2-D/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l3kutu&s=a28486895b89a72d5ab90eac34cecb903250d396" class="inlineGraphic">(acac)(PPh3)3.0.CO;2-D/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l3kutu&s=8166476ddbf4fa6c18ee0ecad44f3ca48f0f67ba" class="inlineGraphic">] und [OsBr3.0.CO;2-D/asset/equation/tex2gif-stack-3.gif?v=1&t=h5l3kutu&s=f4fa904fa1ab08f8e022b31d88bd0cb1d5dfd766" class="inlineGraphic">(acac)(AsPh3)3.0.CO;2-D/asset/equation/tex2gif-stack-4.gif?v=1&t=h5l3kutu&s=10c82754f703fe9aca0254a8b007e17052a2766c" class="inlineGraphic">]

✍ K. Dallmann; W. Preetz 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 110 KB 👁 3 views

K3Au5Pb: eine Schichtstruktur mit 3.0.CO

K3Au5Pb: eine Schichtstruktur mit 3.0.CO;2-V/asset/equation/tex2gif-stack-1.gif?v=1&t=h5l3kijo&s=8216665c8b617423b5e4baac548d48aedbac316c" class="inlineGraphic">[AuAu3/2]-Gold-Tetraedern und 3.0.CO;2-V/asset/equation/tex2gif-stack-2.gif?v=1&t=h5l3kijo&s=32fcde52a59f828b3ae13311d6ea737927d9d41a" class="inlineGraphic">[Pb2/2]-Blei-Ketten

✍ Uwe Zachwieja; Jörg Wlodarski 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 116 KB 👁 2 views

Inhaltsu È bersicht. Silberfarbene, spro È de Einkristalle von K 3 Au 5 Pb wurden durch Umsetzung von Kaliumazid mit Goldschwamm und Bleipulver bei T = 920 K synthetisiert. Die Struktur der Verbindung (Raumgruppe Imma, Z = 4, a = 5,646(1) A Ê , b = 19,500(4) A Ê , c = 8,412(1) A Ê ) wurde aus Ro È n