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Synthesis and studies of polythiophenes substituted with polydeuterated side chains. Isotope effects in the polymerization of 3-alkylthiophenes

✍ Scribed by Gautun, Odd R.; Carlsen, Per H.J.; Samuelsen, Emil J.; Mårdalen, Jostein

Book ID
122490494
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
351 KB
Volume
58
Category
Article
ISSN
0379-6779

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Clear evidence of the sensitivity of the
Clear evidence of the sensitivity of the solvatochromic effect to side chain functionalization in 3-hexyl-substituted polythiophenes
✍ C. Della-Casa; P. Costa-Bizzarri; M. Lanzi; F. Bertinelli 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 461 KB

The solvatochromic properties of 3-hexyl-substituted polythiophenes functionalized with an ester, ether or hydroxy group at the end of the alkyl side chain are reported. An extraordinarily large shift, AA, = 99 nm, and a dramatic change of the UV/ vis spectral profile are found when the carboxylate