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Synthesis and structures of some diorganotin bis(hydroxamate)s

โœ Scribed by V. S. Petrosyan; N. S. Yashina; T. V. Sizova; T. V. Leonova; L. A. Aslanov; A. V. Yatsenko; L. Pellerito


Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
431 KB
Volume
8
Category
Article
ISSN
0268-2605

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Metathesis reaction of ScCl 3 (THF) 3 with 3 equiv. of phenyllithium in THF/Et 2 O solution affords ScPh 3 (THF) 2 (1) in good yield. The crystallographically determined molecular structure of 1 reveals a trigonal-bipyramidal coordination sphere with the THF molecules in the axial positions and ScยฑC