Synthesis and structures of paramagnetic organo titanium fluoride clusters
✍ Scribed by Feng-Quan Liu; Antje Künzel; Axel Herzog; Herbert W Roesky; Mathias Noltemeyer; Roland Fleischer; Dietmar Stalke
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 319 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0277-5387
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## Abstract A brief overview is given of the literature of the use of solvothermal techniques − chemistry in superheated solvents − towards paramagnetic cluster synthesis. Although these techniques have been used extensively to prepare infinite lattice magnetic materials, there is much less work on
The graphite intercalation compound (GIG) of titanium fluoride has been prepared in a fluorine atmosphere. The GICs prepared from natural graphite and pitch-based carbon fiber were mostly stage-2 compounds with repeat distance 11.28-11.59 A and composition Cll\_15TiF4.1\_6 >. The ESCA spectrum indic