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Synthesis and structures of novel enantiopure inherently chiral calix[4]arene-derived salphen ligands and their transition-metal complexes

✍ Scribed by Zhen-Xiang Xu; Zhi-Tang Huang; Chuan-Feng Chen


Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
368 KB
Volume
50
Category
Article
ISSN
0040-4039

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Metal complexes of biologically importan
✍ Roland KrΓ€mer; Kurt Polborn; Christian Robl; Wolfgang Beck πŸ“‚ Article πŸ“… 1992 πŸ› Elsevier Science 🌐 English βš– 606 KB

## Elimination of chloride from Cp\*Rh(L-PheO)Cl with AgBF, leads to the trinuclear complex [Cp\*Rh(p-L-Phe0)],3+(BF4-)3 (Z), in which the amino acidate acts both as an (N, 0)-chelating and as a carboxylate bridging ligand according to the X-ray structural determination. Trimerization of [Cp\*Rh(P