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Synthesis and Structures of (Dialkylamino)ethylcyclopentadienyl Derivatives of Zinc

✍ Scribed by Darensbourg, Donald J.; Wildeson, Jacob R.; Yarbrough, Jason C.


Book ID
127290244
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
87 KB
Volume
20
Category
Article
ISSN
0276-7333

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Synthesis and structure of bis(dialkylam
✍ Akira Nagasawa; Isao Akiyama; Shigeru Mashima; Juzo Nakayama πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 447 KB

## Abstract 2‐Chloro and 2‐phenoxy substituted 1,1‐bis(diethylamino)ethylenes (4a and 4c) react with elemental sulfur at room temperature to give the inner salt, bis(diethylamino)carbeniumdithiocarboxylate (1a), in excellent yields with extrusion of hydrogen chloride and phenol, respectively, thus