Synthesis and Structures of 3,5-disubstituted 1,2,4-triazole Head Units and Incorporation of 3,5-dibenzoyl-1,2,4-triazolate into New [2 + 2] Schiff-Base Macrocyclic Complexes
β Scribed by Brandt, Carsten D.; Kitchen, Jonathan A.; Beckmann, Udo; White, Nicholas G.; Jameson, Geoffrey B.; Brooker, Sally
- Book ID
- 115501358
- Publisher
- Taylor and Francis Group
- Year
- 2007
- Tongue
- English
- Weight
- 312 KB
- Volume
- 19
- Category
- Article
- ISSN
- 1061-0278
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Herein we report an approach to the formation of 5-alkynyl-1,3-dioxin-4-ones using Suzuki-Miyaura cross-coupling reaction of potassium alkynyltrifluoroborate salts with 2,2,6-trimethyl-5-iodo-1,3dioxin-4-one. The resulting 5-ethynyltrimethylsilyl-1,3-dioxin-4-ones obtained through the Sonogashira re
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