Synthesis and structure of uranyl complexes with carboxylic acids and oxygen containing neutral ligands

✍ Scribed by V.I. Spitsyn; R.N. Shchelokov; Yu. N. Mikhailov; K.M. Dunaeva; I.M. Orlova; V.E. Mistrjukov; A.V. Sergeev; V.V. Kolesnik; Z.R. Ashurov

• Publisher: Elsevier Science
• Year: 1984
• Tongue: English
• Weight: 102 KB
• Volume: 94
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)94529-8

✦ Synopsis

1st I.C.L.A. -Papers A (Pi) with a lattice comparable to a pseudo-lamelar structure, intercalated water molecules occupying the interlayer spaces. The substitution of Pd, Pt, Cu to Ni (with Ln = Eu) gives rise to isostructural compounds. Change of solvent (Solvent = (CHa)2SO) does not modify the geometry of the neutral centrosymmetric heteropentanuclear entity, dmso molecules substituting to water molecules. Compounds obtained with M' = Ni,_Ln = Ce, Eu, Er crystallize in the triclinic system (Pl), with CN = 9, n = 5.