Synthesis and Structure of Two New High Nuclearity Ru/Pt Mixed-Metal Clusters
✍ Scribed by Brian F. G. Johnson; Sophie Hermans; Tetyana Khimyak
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 232 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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## Abstract For Abstract see ChemInform Abstract in Full Text.
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The tetrahedral cluster anion [Ru 3 Ir(CO) 13 ] -(1) reacts with neutral hydrido clusters [HRu 2 Ir(CO) 9 (RCϵCRЈ)] (10: R = RЈ = Ph; 11: R = RЈ = Et; 12: R = Ph; RЈ = Me; 13: R = RЈ = Me). internal alkynes RCϵCRЈ to afford the alkyne derivatives [Ru 3 Ir(CO) 11 (RCCRЈ)] -(2: R = RЈ = Ph; 3: R = RЈ