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Synthesis and structure of thetrans-isomer of dimeric 2-(0-aminophenoxymethyl)-2-chloromethyl-1,3,2-benzoxazaphosphole

โœ Scribed by A. N. Chekhlov; A. N. Bovin; E. N. Tsvetkov


Book ID
112386839
Publisher
Springer
Year
1993
Tongue
English
Weight
386 KB
Volume
42
Category
Article
ISSN
1573-9171

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โœ Alexander N. Bovin; Alla N. Yarkevich; Eugene N. Tsvetkov ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 399 KB

The reaction of N,N,O-tris(trimethylsily1)-o-aminophenol with two equivalents of phosphinic chloride yielded dimeric 2,2-disubstituted 1 ,3,2h5-benzoxazaphospholes and trimethylsilyl phosphinate. The chlorides having the bulk substituents (0-chlorophenyl or tert-butyl) at phosphorus or containing P-