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Synthesis and structure of the linear tetranuclear cluster [(MoO2S2)2Fe2S2]4-: implications for aqueous molybdenum-iron-sulfur chemistry

✍ Scribed by Anglin, Robert J.; Kurtz, Donald M.; Kim, Sangsoo; Jacobson, Robert A.


Book ID
121872052
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
415 KB
Volume
26
Category
Article
ISSN
0020-1669

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The homometal cluster [Fe(DMF) 6 ][W 2 (l 2 -S) 2 S 4 ] 1 (DMF = dimethylformamide) was successfully synthesized by low-temperature solid-state reactions. X-ray single-crystal diffraction studies reveal that compound 1 is dinuclear anion cluster. The compound was characterized by elemental analyses,