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Synthesis and Structure of the Intermetallic Lithium Stannides LiTSn4 (T = Ru, Rh, Ir) with Ordered PdGa5 Type Structure

✍ Scribed by Zhiyun Wu; Rolf-Dieter Hoffmann; Rainer Pöttgen


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
221 KB
Volume
628
Category
Article
ISSN
0372-7874

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CaRhIn with TiNiSi Type Structure and Ca
✍ Rolf-Dieter Hoffmann; Rainer Pöttgen 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 174 KB 👁 1 views

CaRhIn, CaRhIn 2 , and CaIrIn 2 were synthesized by reacting the elements in glassy carbon crucibles under an argon atmosphere in a high-frequency furnace. CaRhIn adopts the TiNiSi structure: Pnma, a = 730.0(4) pm, b = 433.1(2) pm, c = 828.8(4) pm, wR2 = 0.0707, 630 F 2 values, 20 variables. The CaR