Synthesis and structure of poly(binaphthyl salen manganese complex) and its application to asymmetric epoxidation

✍ Scribed by Takeshi Maeda; Yoshio Furusho; Toshikazu Takata

• Publisher: John Wiley and Sons
• Year: 2002
• Tongue: English
• Weight: 108 KB
• Volume: 14
• Category: Article
• ISSN: 0899-0042
• DOI: 10.1002/chir.10093

✦ Synopsis

Poly(binaphthyl salen manganese complex)es 3-Mn were synthesized from a 3,3'-diformylbinaphthol derivative, alpha,omega-diamines, and Mn(OAc)2. Their helical structures were well-supported by their IR, UV, and CD spectra. The catalysis of 3-Mn in an asymmetric epoxidation was investigated.