Synthesis and Structure of P,N-Heterodifunctional Ferrocene Ligands and their Transition Metal Complexes for Palladium-Catalyzed Aryl Amination Reaction

✍ Scribed by Pedro Molina; Antonio Arques; Alejandro García; M.Carmen Ramírez de Arellano

• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 539 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)01807-8

✦ Synopsis

The.Vatidingerreactionof the ~ferrocenylvinykzzide1 with di-and triphosphinesprovided a new rangeof P, N-heterodiJimctional ferroceneligandsbearingan iminophosphorane and at least a diphenylphosphinogroup; reactivity towank Pd (II) and the ability of the resulting complexesfor palladiumcatalyzedaryl aminationreactionis described. @ 1997Elsevier

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