A wide variety of isostructural phases of the NZP family, \(A M^{\prime 3}{ }^{\prime \prime}{ }^{\prime 4} \mathrm{P}_{3} \mathrm{O}_{12}\), have been synthesized. Some of these phases are reported for the first time. Characterizations by IR, EPR, and UV-visible spectroscopic methods are presented.
Synthesis and Structure of Phases Containing [Ni3P3S12]3- Crown-Shaped Trimers.
β Scribed by Martine Bujoli-Doeuff; Servane Coste; Michel Evain; Raymond Brec; Dominique Massiot; Stephane Jobic
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 34 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The new cubic compound Fe 0.5 Ni 0.5 P 3 (a = 775.29(5) pm) as well as the known compounds CoP 3 and NiP 3 were synthesized from the elemental components using tin as a flux. Their skutterudite (CoAs 3 ) type structures were refined from single-crystal X-ray data. The new compound GdFe 4 P 12 was pr