Synthesis and Structure of Orobanchol, the Germination Stimulant for Orobanche minor
โ Scribed by Junichi Matsui; Takao Yokota; Masahiko Bando; Yasutomo Takeuchi; Kenji Mori
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 395 KB
- Volume
- 1999
- Category
- Article
- ISSN
- 1434-193X
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โฆ Synopsis
Scheme 1. Structures of the germination stimulants [a
๐ SIMILAR VOLUMES
assigned on the basis of an X-ray analysis of (ยฑ)-3a, which [a] Department of Chemistry, Faculty of Science, Science Univerwas obtained from (ยฑ)-7. Treatment of (ยฑ)-7 with alumisity of Tokyo, num isopropoxide in toluene under reflux for 5 h followed Kagurazaka 1ฯช3,
The potent seed germination stimulants (+)-strigol (1), (+)-2ะ-bisepiorobanchol (2ะะะ)] were prepared from the enantiomers of 3, which were obtainable by lipase-catalyzed orobanchol (2) and their stereoisomers [2ะ-epistrigol (1ะ), ent-1, ent-1ะ, 2ะ-epiorobanchol (2ะ), 4-epiorobanchol (2ะะ) and 4, en