Synthesis and Structure of Novel Complexes of Gallium
β Scribed by Eva Leiner; Oliver Hampe; Manfred Scheer
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 464 KB
- Volume
- 2002
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The Β΅ 3 -boryloxycarbyne complexes [{Fe(CO) 3 } 3 {Β΅ 3 -COBCl-dichlorodiboranes(4) B 2 (NMe 2 ) 2 Cl 2 , respectively. The products are formed by a nucleophilic attack of the CO {NtBu( SiMe 3 )}} 2 ] (1) and[{(Ξ· 5 -C 5 H 5 )Ni} 3 {Β΅ 3 -COBX(NR 2 )}Β΅ 3 -CO] (2a: NR 2 = NtBu(SiMe 3 ), X = Cl; 2b: NR 2
The new tetraazido complexes of aluminium, gallium, and indium [thf 2 Na][thf 2 Al(N 3 ) 4 ] (1), [py 2 Na][py 2 In(N 3 ) 4 ] (2), andNa[Ga(N 3 ) 4 ] (3) have been synthesized from MCl 3 and NaN 3 by salt metatheses and characterized by X-ray diffraction analysis. In compounds 1 and 2, the Group 13