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Synthesis and structure of new framework phosphates Li1/4M7/4(PO4)3(M= Nb, Ta)

✍ Scribed by M. V. Sukhanov; E. R. Gobechiya; Yu. K. Kabalov; V. I. Pet’kov


Book ID
111438023
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
381 KB
Volume
53
Category
Article
ISSN
1063-7745

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Synthesis and Structure of Two New Quate
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Two new quaternary nitrides, Li 3 Sr 2 M N (M‫؍‬Nb, Ta) have been synthesized from Li, Sr, and Nb or Ta metals under a flowing Ar-NH 3 atmosphere at 800°C under ambient pressure. The structures, determined by single crystal X-ray diffraction, are orthorhombic, space group Pnnm (No. 58) with Z‫,4؍‬ a