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Synthesis and Structure of New Cd−Bi−S Homologous Series: A Study in Intergrowth and the Control of Twinning Patterns

✍ Scribed by Choe, Wonyoung; Lee, Stephen; O'Connel, Patrick; Covey, Aaron

Book ID
126069498
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
141 KB
Volume
9
Category
Article
ISSN
0897-4756

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✍ Antje Mrotzek; Mercouri G. Kanatzidis 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 331 KB

Both the composition and structure of A 1Àx Sn 9Àx Bi 11+x Se 26 (A=K, Rb, Cs) were predicted on the basis of the homologous series A m [M 6 Se 8 ] m [M 5+n Se 9+n ] (M=Sn, Bi) and targeted for synthesis. A 1Àx Sn 9Àx Bi 11+x Se 26 adopts a new structure type that fits the structural evolution of th