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Synthesis and structure of N′-(2-phenylaminobenzoyl)hydrazones of aromatic aldehydes, ketones, and α-dicarbonyl compounds

✍ Scribed by F. V. Bagrov


Book ID
110666395
Publisher
SP MAIK Nauka/Interperiodica
Year
2000
Tongue
English
Weight
343 KB
Volume
36
Category
Article
ISSN
1023-1935

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Asymmetric ot-sulfenylation of lithiated SAMP/RAMP hydrazoncs (3")-2 with disulfides afforded tz-thiolated hydrazones (S,R)-3 in good yields (48-87%) and high diastcreomeric excesses (91-96%). Subsequent oxidative cleavage or acidic hydrolysis of the hydrazones furnished a-thiolated ketones (R)-4a.d