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Synthesis and Structure of Heterometallic Clusters (IrCo 2 , IrFe) Containing Bridging 1,2-Dicarba- c loso -dodecaborane-1,2-dichalocogenolato Ligands

โœ Scribed by Wang, Jian-Qiang; Hou, Xiufeng; Weng, Linhong; Jin, Guo-Xin

Book ID
126440584
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
146 KB
Volume
24
Category
Article
ISSN
0276-7333

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The reaction of [Cp\*IrCl 2 ] 2 with dilithium 1,2-ortho-{Se 2 C 2 (B 10 H 10 )}] (5). The molecular structures of 4 and 5 were determined by X-ray crystal structure analysis. The 77 Se-carborane-1,2-diselenolate 3 leads to the green 16-electron diselenolene complex [Cp\*Ir{Se 2 C 2 (B 10 H 10 )}] (