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Synthesis and Structure of Heterodinuclear Rhodium and Iridium Borylene Complexes

✍ Scribed by Holger Braunschweig; Melanie Forster; Fabian Seeler


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
293 KB
Volume
15
Category
Article
ISSN
0947-6539

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Treatment of [[M(mu-Cl)(diolefin)](2)] with the lithium salts of primary and secondary amines (LiNRR') in diethyl ether affords the complexes [[M(mu-NRR')(diolefin)](2)] (M=Rh, Ir; diolefin=1,5-cyclooctadiene (cod), tetrafluorobenzobarrelene (tfb); R'=H, R=tBu, Ph, 4-MeC(6)H(4); R=R'=Ph, 4-MeC(6)H(4