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Synthesis and Structure of Functionalized Cyclododecadiynes and -dienes

✍ Scribed by Christoph Boss; Reinhart Keese

Publisher
John Wiley and Sons
Year
1996
Tongue
German
Weight
895 KB
Volume
79
Category
Article
ISSN
0018-019X

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✦ Synopsis

Cyclic diallenes and allen-ynes have been obtained from activated 3a, Sa, as well as from 13a by Cul-induced alkylation via 1,3-substitution reactions [14].

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ChemInform Abstract: Synthesis and Struc
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Synthesis and Structure of Functionalized Cyclododecadiynes anddienes. -Starting from open-chain 1,7-diynes title compounds such as (VI) and ( XII)-(XIV) are obtained by N,N'-dimethylpropyleneurea-assisted ring-closing alkylation.