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Synthesis and structure of cycloruthenated carbonyl complexes and their emission, redox and biological properties

✍ Scribed by K. Naresh Kumar; R. Ramesh; Yu Liu

Book ID
108174907
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
297 KB
Volume
100
Category
Article
ISSN
0162-0134

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A simple and convenient synthesis of a new class of air-stable mononuclear cyclometallated ruthenium(II) carbonyl 2-(arylazo)phenolate complexes bearing triphenylarsine [Ru(ap-R)(AsPh 3 ) 2 (CO)] has been described. The 2-(arylazo)phenolate ligands behave as dianionic tridentate ligands and are coor