Synthesis and Structure of Cyclic Phosphate, Phosphoramidate, Phosphonates, and Phosphonium Salts. Phosphatrane Formation 1
β Scribed by Chandrasekaran, A.; Day, Roberta O.; Holmes, Robert R.
- Book ID
- 126334849
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 104 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0020-1669
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The synthesis of a new pentacovalent oxaphospholene from a dienone, and its use as an enolate equivalent in the approach toward the syntheses of phosphonate analogs of sphingomyelin, sphingosine 1-phosphate and ceramide 1-phosphate are described. Condensation of the new P(V) reagent with an azodicar