𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and structure of cobaltocenium salt [Co(C5H5)2]2Os1.5Cl9·4H2O

✍ Scribed by I. P. Bakhvalova; A. D. Vasilyev; A. I. Kruglik; L. A. Solovyev

Book ID
110563711
Publisher
SP MAIK Nauka/Interperiodica
Year
1994
Tongue
English
Weight
448 KB
Volume
35
Category
Article
ISSN
0022-4766

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Anion Binding of 1,1′-Bis(dialkylboryl)c
Anion Binding of 1,1′-Bis(dialkylboryl)cobaltocenium Complexes − Structures of [Co{C5H4(BMe2)}2]PF6, Co[C5H4(BMe2)][C5H4(BMe2Cl)], Co[C5H4(BiPr2)]2(µ-F) and NMe4[Co{C5H4(BiPr2F)}2]
✍ Gerhard E. Herberich; Ulli Englert; Andreas Fischer; Dag Wiebelhaus 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 212 KB

## Abstract The cobaltocenium salts [Co{C~5~H~4~(B__i__Pr~2~)}~2~]PF~6~ [(1a)PF~6~] and [Co{C~5~H~4~(BMe~2~)}~2~]PF~6~ [(1b)PF~6~] are strong Lewis acids. With pyridine (1a)PF~6~ forms a mono‐adduct 2 and a di‐adduct 3 which show NMR spectra in the low‐temperature regime of pyridine exchange. With