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Synthesis and Structure of (CO)4W[C(NEt2)PMePh], A Novel Cyclic Carbene Complex

✍ Scribed by Prof. Dr. Ernst Otto Fischer; Rudolf Reitmeier; Dr. Klaus Ackermann


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
223 KB
Volume
22
Category
Article
ISSN
0044-8249

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✦ Synopsis


with difficulty. We report here a versatile synthetic pathway leading to syn-benzene dioxides and their dioxocin valence tautomers via a Diels-Alder route.


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Synthesis and Structure of a (Carbene)(Ξ·
✍ Dipl.-Chem. Klaus Angermund; Dr. Friedrich-Wilhelm Grevels; Prof. Dr. Carl KrΓΌge πŸ“‚ Article πŸ“… 1984 πŸ› John Wiley and Sons 🌐 English βš– 244 KB

E, they are also not hydrolyzed by conc. hydrochloric acid. 3a-c can be deprotonated with sodium hydroxide and acylated at the nitrogen. Although in the 1,2,4-diazaphospholes a 1,3-diamino-2phosphaallyl system is still formally present, the ring closure is associated with an essential change: the c