The bis(1,2,3,4,5-pentamethyl-1,3-cyclopentadien-1-yl)phos-also been characterized by single-crystal X-ray diffraction studies. The molecular structure of 11a is governed by steric phanes 3Οͺ7 are formed in good yields by the reaction of the halogenophosphanes 2a or 2b with the appropriate nucle-cong
Synthesis and structure of bis(pentamethylcyclopentadienyl) selenium
β Scribed by C.Matthew Bates; Christopher P. Morley; Michael B. Hursthouse; K.M.Abdul Malik
- Book ID
- 103231100
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 150 KB
- Volume
- 489
- Category
- Article
- ISSN
- 0022-328X
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## Reactivity of Cobalt Atoms towards 1,2,3,4,5-Pentamethylcyclopentadienyl: Synthesis and Structure of Bis(q5-pentamethylcyclopentadienyl)-(p2-q5 :q5-pentamethy1cyclopentadienyl)dicobalt and Bis(q5-pentamethylcyclopentadienyl)dicobalt \*\*
## Bis(pentamethylcyclopentadienyl)phosphane Cp\* 2 PH reacts with sulfur under basic conditions to give the corresponding dithiophosphinate salts M β«Χβ¬ (5 β«Χβ¬ CP\* PS 2 2 M β«Χβ¬ β«Χ‘β¬ , 6 M β«Χβ¬ β«Χ‘β¬ Li β«Χβ¬ ), which are formed via the β«Χβ¬ HNEt 3 intermediate CP\* 2 P(S)H (4). Both salts on treatment wi