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Synthesis and Structure of Ba5(V2O7)2Cl2

✍ Scribed by K. G. Sanjaya Ranmohotti; Wendy L. Queen; J. Palmer West; Don VanDerveer; Shiou-Jyh Hwu


Publisher
Springer
Year
2008
Tongue
English
Weight
335 KB
Volume
39
Category
Article
ISSN
1572-8854

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KMo 2 O 2 Cl 7 was obtained at 400 Β°C from the reaction of SCl 2 with molybdenum which contained traces of potassium. Its crystal structure is monoclinic, space group C2/c, a = 1094.1, b = 1139.1, c = 1018.0 pm, b = 110.16Β°, Z = 4. In the Mo 2 O 2 Cl 7 Β± ion two coordination octahedra share a common