Synthesis and Structure of Ba5(V2O7)2Cl2
β Scribed by K. G. Sanjaya Ranmohotti; Wendy L. Queen; J. Palmer West; Don VanDerveer; Shiou-Jyh Hwu
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 335 KB
- Volume
- 39
- Category
- Article
- ISSN
- 1572-8854
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π SIMILAR VOLUMES
Crystals of ordered and disordered Ba 7 F 12 Cl 2 were prepared by flux growth and solid state reactions. These new structures were characterized by single crystal and powder X-ray diffraction. The disordered variant which shows disorder on one of the cation sites was obtained from a BaF 2 + BaCl 2
Two new \(\mathrm{Fe}^{\mathrm{Ill}}\) and \(\mathrm{V}^{\mathrm{ll}}\) phosphates, \(\mathrm{Ba}_{2} \mathrm{Fe}_{3} \mathrm{H}\left(\mathrm{PO}_{4}\right)_{2}\left(\mathrm{P}_{2} \mathrm{O}_{7}\right)_{2}\) and \(\mathrm{Ba}_{2} \mathrm{~V}_{3} \mathrm{H}_{2}\left(\mathrm{PO}_{4}\right)_{2}\left(\
KMo 2 O 2 Cl 7 was obtained at 400 Β°C from the reaction of SCl 2 with molybdenum which contained traces of potassium. Its crystal structure is monoclinic, space group C2/c, a = 1094.1, b = 1139.1, c = 1018.0 pm, b = 110.16Β°, Z = 4. In the Mo 2 O 2 Cl 7 Β± ion two coordination octahedra share a common