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Synthesis and Structure of Ba 2 Sn 3 Sb 6 , a Zintl Phase Containing Channels and Chains

✍ Scribed by Lam, Robert; Mar, Arthur


Book ID
126487169
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
229 KB
Volume
35
Category
Article
ISSN
0020-1669

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Two Ternary Phases Containing Sb4βˆ’2 Ions
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The isotypic compounds Na 2 Ba 3 Sb 4 and Na 2 Sr 3 Sb 4 were prepared by the direct fusion of elements at 7503C followed by slow cooling to, and annealing at, 3003C. These crystallize in the orthorhombic system, space group Pnma (No. 62), with respective lattice dimensions of a ‫؍‬ 8.220(1), 7.919(