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Synthesis and structure of an ortho-metallated ketazine complex of osmium, tsqbOsH(CO)2[(C6H3-p-Me)(p-tolyl)CNNC(p-tolyl)2](PPh3)

โœ Scribed by M.A. Gallop; C.E.F. Rickard; W.R. Roper


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
492 KB
Volume
395
Category
Article
ISSN
0022-328X

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Synthesis of a New Multidentate Phosphan
โœ Pablo Steenwinkel; Sebastiaan Kolmschot; Robert A. Gossage; Paulo Dani; Nora Vel ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 581 KB

The tetrakis(phosphane oxide) C 6 H 2 {CH 2 P(O)Ph 2 } 4 -1,2,4,5 (5), has been prepared in high yield from the Arbuzov reaction of C 6 H 2 (CH 2 Br) 4 -1,2,4,5 (4), with excess (7 equiv.) of Ph 2 POEt. Subsequent reduction of 5 with HSiCl 3 (12 equiv.) in C 6 H 4 Cl 2 -1,2 afforded the new tetrapho