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Synthesis and Structure of Acetonitrile Solvates of Copper(II) Monofluoroacetate and Silver(I) Trifluoroacetate, [Cu2(CH2FCOO)4· 2CH3CN](CH3CN) and Ag3(CF3COO)3(CH3CN)2

✍ Scribed by E. V. Karpova; A. I. Boltalin; Yu. M. Korenev; M. A. Zakharov; S. I. Troyanov

Book ID
110299808
Publisher
SP MAIK Nauka/Interperiodica
Year
2001
Tongue
English
Weight
81 KB
Volume
27
Category
Article
ISSN
1070-3284

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✍ S. V. Pasenok; N. V. Kirij; Yu. L. Yagupolskii; D. Naumann; W. Tyrra; A. Fitzner 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 93 KB 👁 1 views

The reactions of Zn(CF 3 )Br ´2 CH 3 CN, Cd(CF 3 ) 2 ´2 CH 3 CN or Bi(CF 3 ) 3 /AlCl 3 with tertiary amines lead to the formation of quaternary ammonium salts of the general formula [R 3 NCF 2 H]X. The reaction of 4-N,N-dimethylaminopyridine with Zn(CF 3 )Br ´2 CH 3 CN yields (Ndifluoromethyl)-4-N,N