Synthesis and structure of a novel dinuclear copper(II) complex containing 1,4,7-triazacyclododecane [Cu2(HO) (MeCO2) (tacd)2](Cl04)2
β Scribed by Xiao-Ming Chen; Xiao-Lan Yu; Yu-Xing Yao; Xiao-Ying Huang
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 256 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0277-5387
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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OHΒ±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Γ , b = 107.105(3)Β°,
Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 Β΄6 H 2 O were obtained from a CH 3 OHΒ±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Γ
## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4βisobutylβ3,5βdi(2βpyridyl)β4__H__β1,2,4βtriazole (ibdpt) with M(ClO~4~)~2~Β·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~