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Synthesis and Structure of a Novel Cluster with Trigonal-bipyramidal Ge2Ru3 Core

✍ Scribed by Yong-Qiang Zhang; Bai-Quan Wang; Shan-Sheng Xu; Xiu-Zhong Zhou


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
329 KB
Volume
20
Category
Article
ISSN
0256-7660

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Synthesis and Structure of [Hg{OP(O)CF3(
✍ Ingo Pantenburg; Christoph ThΓΆsen; Berthold Hoge πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 German βš– 126 KB πŸ‘ 1 views

The hydrolysis of [Hg{P(CF 3 ) 2 } 2 (PMe 3 ) 2 ] yields colourless crystals of [Hg{OP(O)CF 3 (OH)} 2 (PMe 3 ) 3 ]. The proposed multistep reaction proceeds via primary hydrolysis of the starting material giving HgO and HP(CF 3 ) 2 . The latter is directly oxidized by HgO to (CF 3 ) 2 P(O)OH. The bi