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Synthesis and structure of a new 1,2-bridged calix[6]arene

โœ Scribed by Haberz, Peter; Belaj, Ferdinand; Gloe, Karsten; Wentrup, Curt; Kollenz, Gert

Book ID
118041813
Publisher
Taylor and Francis Group
Year
2012
Tongue
English
Weight
268 KB
Volume
24
Category
Article
ISSN
1061-0278

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Synthesis of 1,2-bridged calix[4]arene-b
Synthesis of 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation
โœ Arturo Arduini; Laura Domiano; Andrea Pochini; Andrea Secchi; Rocco Ungaro; Fran ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 505 KB

New methods to obtain 1,2-bridged calix[4]arene-biscrowns in the 1,2-alternate conformation are described. The stereochemistry of the proximal double functionalization reaction is mainly governed by the solvent, the length of the polyether units and the base used to deprotonate the calix[4]arene.