Synthesis and Structure of a Linked-Bis(amidate) Ligand and Some Complexes with Titanium
β Scribed by Giesbrecht, Garth R.; Shafir, Alex; Arnold, John
- Book ID
- 127189110
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 55 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
Two ligand bridged binuclear titanium complexes Ti 2 (bppda) 3 (NMe 2 ) 2 β’3THF (1) and Ti 2 (bppda) 3 (NEt 2 ) 2 β’3THF (2) and one bis-ligand coordinated mononuclear complex Ti(bppda) 2 (3) (ligand: H 2 bppdaοΌN,N'-Bis(2-pyrrylmethylidene)-1,2-phenylenediamine) were synthesized by adjusting the rat
Titanium complexes containing a linked isopropyl-or benz-{C 6 H 4 (CH 2 NMe 2 )-2}Cl and of Ti(Ξ· 5 :Ξ· 1 -C 5 Me 4 SiMe 2 NiPr)-{CH 2 C 6 H 4 (NMe 2 )-2}Cl revealed the presence of intramolecu-ylamido(tetramethylcyclopentadienyl) ligand C 5 Me 4 Si-Me 2 NR (R = iPr, CH 2 Ph,) and one bidentate organy