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Synthesis and structure of a diiron divinylidene complex formed by oxidative carbon-carbon coupling

✍ Scribed by Iyer, Ramnath S.; Selegue, John P.

Book ID: 127146993
Publisher: American Chemical Society
Year: 1987
Tongue: English
Weight: 288 KB
Volume: 109
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00237a052

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## Abstract The heterobimetallic complexes [(η^5^‐C~5~H~5~)Ru(CO)(μ‐dppm)Mn(CO)~4~] and [(η^5^‐C~5~Me~5~)Ru(μ‐dppm)(μ‐CO)~2~Mn(CO)~3~] (dppm= bis‐diphenylphosphinomethane) have been prepared by reacting the hydridic complexes [(η^5^‐C~5~H~5~)Ru(dppm)H] and [(η^5^‐C~5~Me~5~)Ru(dppm)H], respectively,