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Synthesis and Structure of a Digallane with Tris(trimethylsilyl)silyl and Chloro Substituents

✍ Scribed by Dr. Gerald Linti; Dipl.-Chem. Wolfgang Köstler


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
421 KB
Volume
35
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Synthesis and Structure of Methoxybis[tr
✍ Jeschke, Elke ;Gross, Thoralf ;Reinke, Helmut ;Oehme, Hartmut 📂 Article 📅 1996 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 469 KB 👁 2 views

Methane, methoxybis[tris(trimethylsilyl)silyl-/ Tris(trimethylsily1)silyllithium / Dichloromethyl methyl ether / ## Poly silanes Methoxy-bis[tris(trimethylsilyl)silyl]methane (4), the first compound bearing two hypersilyl groups at a carbon atom, was synthesized by the reaction of tris(trimethyls

The Reaction of Transient 1,1-Bis(trimet
✍ Katrin Sternberg; Helmut Reinke; Hartmut Oehme 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 170 KB 👁 2 views

Tris(trimethylsilyl)silyllithium (3) reacted with aldehydes and ketones (molar ratio 2 : 1) according to a modified Peterson mechanism under formation of transient silenes, which were immediately trapped by excess 3 to give the organolithium derivatives (Me 3 Si) 3 SiSi(SiMe 3 ) 2 C(Li) Ŕ1 R 2 (7).