𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis and Structure Determination of Rh−diene Complexes with the Hydridotris(3,5-diisopropylpyrazolyl)borate Ligand, Tp iPr Rh(diene) (diene = cod, nbd): Dependence of the ν(B−H) Values on the Hapticity of the Tp iPr Ligand (κ 2 vs κ 3 ) 1

✍ Scribed by Akita, Munetaka; Ohta, Keisuke; Takahashi, Yoshiaki; Hikichi, Shiro; Moro-oka, Yoshihiko

Book ID
126792787
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
270 KB
Volume
16
Category
Article
ISSN
0276-7333

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis of a Series of Rhodium Complex
Synthesis of a Series of Rhodium Complexes, Tp iPr Rh I L 2 and Tp iPr Rh III (X)(Y)(MeCN), with the Hydridotris(3,5-diisopropylpyrazolyl)borato Ligand (Tp iPr ) from a Versatile Precursor, (κ 3 -Tp iPr )Rh(coe)(MeCN), and Dependence of κ 2 −κ 3 Interconversion Rate of the Tp iPr Ligand on the Chelate Ring Size
✍ Ohta, Keisuke; Hashimoto, Mariko; Takahashi, Yoshiaki; Hikichi, Shiro; Akita, Mu 📂 Article 📅 1999 🏛 American Chemical Society 🌐 English ⚖ 91 KB
Synthesis and Structure of [Tp*Rh{P(C7H7
Synthesis and Structure of [Tp*Rh{P(C7H7)3}] – Competition between the Ligands Tris(3,5-dimethyl-1-pyrazolyl)borate (Tp*) and Tris(1-cyclohepta-2,4,6-trienyl)phosphane. Proof of the κ2(N,B–H) Coordination Mode of the Tp* Ligand
✍ Max Herberhold; Stefan Eibl; Wolfgang Milius; Bernd Wrackmeyer 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 107 KB 👁 1 views

Stepwise introduction of the potential tripod ligands tris(3,5-dimethyl-1-pyrazolyl)borate (Tp\*) and tris(1cyclohepta-2,4,6-trienyl)phosphane into the coordination sphere of rhodium(I) leads mainly to [Tp\*Rh{P(C 7 H 7 ) 3 }] (4), in which Tp\* is linked to the rhodium through a single pyrazolyl gr