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Synthesis and structural studies of hydrazino-crown ethers and thermodynamic studies of their interaction with transition, and post-transition metal ions and methyl ammonium ion

โœ Scribed by N. Kent Dalley; Weiming Jiang; Krzysztof E. Krakowiak; Geng Wu; D. Wade Walke; Jerald S. Bradshaw; Reed M. Izatt

Publisher
Springer Netherlands
Year
1990
Tongue
English
Weight
497 KB
Volume
8
Category
Article
ISSN
0923-0750

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The kinetics of reversible complexation of Ni lI and Co Il with iminodiacetato(pentaammine)cobalt(III), [(NH3) 5-Co(idaH2)] 3+ and Ni II with iminodiacetato(tetraammine)cobalt(III), [(NH3)4Co(idaH)] 2 +, have been investigated by the stopped-flow technique at 25 ~ pH = 5.7-6.9 and I = 0.3 tool dm-3.