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Synthesis and structural studies of bridgehead dienes: 3 - oxobicyclo[6.3.1]dodeca -1(11),8(9) - diene - (zz) -11- carboxylic acid and 3 - oxobicyclo[7.3.1]trideca -1(12),9(10) - diene - (zz) - 12 - carboxylic acid

โœ Scribed by K.J. Shea; L.D. Burke; Robert J. Doedens


Book ID
108371796
Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
431 KB
Volume
42
Category
Article
ISSN
0040-4020

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Structural studies of bridgehead alkenes
โœ K.J. Shea; David K. Cooper; W.P. England; Joseph W. Ziller; Timothy G. Lease ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 269 KB

## TheX -ray crystal structure of 3-oxnbicyclo[53.Il&ca-I(1O).7(8)-(zz)-diene-IO-carboxylic acid, a highly strained bridgehead diem?, is reported. Bridgehead alkenes (1) comprise a subclass of trarrscycloallcenes ( 2), compounds that contain a distorted carbon-carbon double bond.' The magnitude of