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Synthesis and Structural Investigation of a Series of Noncentrosymmetric Cyclohexaphosphates: M(C6H5NH3)4P6O18⋅8H2O (M: Cd, Cu, Co)

✍ Scribed by S. Abid; M. Rzaigui


Publisher
Springer
Year
2005
Tongue
English
Weight
366 KB
Volume
16
Category
Article
ISSN
1040-0400

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Synthesis and crystal structure of a new
✍ O. Amri; S. Abid; M. Rzaigui 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 220 KB

Single crystals of (4-ClC 7 H 6 NH 3 ) 9 [Nd(P 6 O 18 ) 2 ].9H 2 O were synthesized in aqueous solution. This compound crystallizes in a triclinic P1 unit-cell, with a = 14.898( 6), b = 18.049( 7), c = 20.695(6)Å, α = 102.04(3), β = 100.49(3), γ = 98.82(3)°, V = 5245(4) 3 Å and Z = 2. The crystal s