Synthesis and Structural Features of New Ruthenium(II) Complexes Containing the Scorpionate Ligands Tris(pyrazol-1-yl)methanesulfonate (Tpms) and Tris(pyrazol-1-yl)methane (Tpm)
✍ Scribed by Sara Miguel; Josefina Diez; Ma Pilar Gamasa; Ma Elena Lastra
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 607 KB
- Volume
- 2011
- Category
- Article
- ISSN
- 1434-1948
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## Abstract A series of ruthenium(II) complexes with the pyrazolylalkane ligands bis(pyrazol‐1‐yl)methane (BPM) (I) and bis(3,5‐dimethylpyrazol‐1‐yl)methane (dmBPM) (II), and the imidazolylalkane ligand bis(__N__‐methylimidazol‐2‐yl)methane (BIM) (III) have been synthesised and characterised. The c
## Abstract Modification of the multistep synthesis of the previously described bis[5‐(diphenylphosphanyl)pyrazol‐1‐yl)]methane (bppzm, 1) produces the novel diphosphane (diphenylphosphanyl)‐[5‐(diphenylphosphanyl)pyrazol‐1‐yl](pyrazol‐1‐yl)methane (p4m, 2). Treatment of this ligand with [MCl~2~(Ph