Synthesis and structural characterization of the normal spinel Li[Ni2]O4
β Scribed by M.G.S.R. Thomas; W.I.F. David; J.B. Goodenough; P. Groves
- Book ID
- 113186990
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 413 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0025-5408
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A new process for the synthesis of well-crystallized lithium manganese spinels with a homogenous composition Li 1Ψx Mn 2Ψx O 4 (04x40.333) has been developed using the stoichiometry mixture of lithium acetate LiOAc and manganese nitrate Mn(NO 3 ) 2 as starting materials. The decomposition of the raw
packed structures was further extended by Goodenough's group to 3-D materials with the spinel structure (3). It was Lithium manganospinels belonging to the LiMn 2 O 4 -Li 2 Mn 4 O 9 -Li 4 Mn 5 O 12 system were prepared by solid-state reac-shown that lithium could be intercalated into the spinels tio