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Synthesis and structural characterization of the C-6 fluoroalkylated pyrimidine derivatives

✍ Scribed by Svjetlana Krištafor; Tatjana Gazivoda; Mario Cetina; Damjan Makuc; Janez Plavec; Silvana Raić-Malić


Book ID
104058977
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
428 KB
Volume
923
Category
Article
ISSN
0022-2860

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The titanocene vinylidene intermediate [Cp\* 2 Ti=C=CH 2 ] (9) The azatitanacyclobutane [Cp\* 2 Ti{ϪNPhϪC(Ph)(H)Ϫ(C= CH 2 )Ϫ}] (22) was formed from the reaction between 9 and reacted with the carbodiimides RϪN=C=NϪR [R = p-CH 3 C 6 H 4 (19a), C 6 H 11 (19b)] to give the N=C-cycloaddition benzylidene