Synthesis and structural characterization of strontium- and magnesium-co-substituted β-tricalcium phosphate

✍ Scribed by S. Kannan; F. Goetz-Neunhoeffer; J. Neubauer; S. Pina; P.M.C. Torres; J.M.F. Ferreira

• Publisher: Elsevier Science
• Year: 2010
• Tongue: English
• Weight: 540 KB
• Volume: 6
• Category: Article
• ISSN: 1742-7061
• DOI: 10.1016/j.actbio.2009.08.009

✦ Synopsis

The synthesis of five different Sr(2+)- and Mg(2+)-co-substituted beta-tricalcium phosphate (beta-TCP) has been obtained by heating the calcium-deficient apatites above 800 degrees C. With the investigated concentrations of Sr(2+) and Mg(2+) from the present study, no additional phases other than beta-TCP have been detected. The synthesized powders have been characterized by X-ray diffraction, Fourier transform infrared spectrometry, elemental analysis and Rietveld refinement studies. The co-substitution of Sr(2+) and Mg(2+) in the beta-TCP has resulted in the formation of crystalline beta-TCP at hexagonal setting (space group R3c). The reduction of lattice a- and c-axis parameters with the combined substitution of Sr(2+) and Mg(2+) in the beta-TCP has been found evident from the present results. Sr(2+) has been found occupying the Ca(1,2,3,4) sites and Mg(2+) was found at the sixfold coordinated Ca(5) site of beta-TCP structure.