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Synthesis and structural characterization of novel symmetric homodinuclear iridium acetylacetonate complexes

✍ Scribed by Chang, Qiaowen; Yan, Caixian; Jiang, Jing; Chen, Jialin; Ye, Qingsong; Yu, Juan; Liu, Weiping

Book ID
125522838
Publisher
Springer Netherlands
Year
2014
Tongue
English
Weight
455 KB
Volume
41
Category
Article
ISSN
0922-6168

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Synthesis and Structural Characterizatio
Synthesis and Structural Characterization of Pincer Pyridine Diphosphite Complexes of Rhodium and Iridium
✍ Miguel Rubio; AndrΓ©s SuΓ‘rez; Esmeralda Vega; Eleuterio Álvarez; Josefina DΓ­ez; M πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 586 KB

## Abstract The synthesis of a novel pyridine diphosphite ligand 1 has been described. From this ligand, rhodium– and iridium–chlorido complexes of formula [MCl(1)] (M = Rh, Ir) have been prepared. Chloride abstraction by treatment with NaBPh~4~ and a phosphane produced the corresponding cationic p