Synthesis and Structural Characterization of Novel Silenes Stabilized by Intramolecular Coordination of a Dialkylamino Group

Distorted Germyllithium Induced by Intra

Distorted Germyllithium Induced by Intramolecular Coordination of an Amino Group: Synthesis and Structures of {Tris[2-(dimethylamino)phenyl]germyl}lithium

✍ Atsushi Kawachi; Yoko Tanaka; Kohei Tamao 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 213 KB 👁 1 views

{Tris [2-(dimethylamino)phenyl]germyl}lithium (1) has been amino group induces the distortion of the geometry around the germanium atom. In solution, however, two species exist prepared. The X-ray analysis shows that 1 exists as a monochelated monomer in the solid state, where the lithium as evidenc