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Synthesis and Structural Characterization of Hydrazine Bridged Imidazole and its Fumarate Salt

โœ Scribed by Shouwen Jin; Daqi Wang


Book ID
113070429
Publisher
Springer
Year
2011
Tongue
English
Weight
283 KB
Volume
42
Category
Article
ISSN
1572-8854

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## Bridged thiazolium salts (6a,b) have been synthesized using macrolactonisation techniques to make the corresponding thiazolinethiones (4a,b) followed by treatment with H202. For each compound the bridge exists predominantly in a single conformation which has been determined both by n.m.r. and X-r

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] n 1 has been synthesized and structurally characterized. Compound 1 is monoclinic, P2 1 / c with unit cell parameters a = 8.8759(9) ร…, b = 11.4112(11) ร…, c = 8.8908(9) ร…, b = 106.010(6)ยฐ, V = 865.6(1) ร… 3 , Z = 2 and D calc. = 1.600 g cm ร€3 . The structure refined to R 1 = 0.0245, wR 2 = 0.0626 fo